Zeolite Molecular Sieves in Oxygen Concentrators: LiX and NaX

Full Compatibility

Cartridges fit most stationary and portable concentrators.

Flexible Packaging

Available in packages from small containers to 200-liter drums – we adapt to your logistical needs.

Professional Advice

We assist in choosing the right sieve type – technical consultancy based on experience.

Molecular Sieve Cartridges for Oxygen Concentrators

Molecular sieves are key components of oxygen concentrators using PSA (Pressure Swing Adsorption) or VPSA (Vacuum Pressure Swing Adsorption) technology. Their precise pore structure effectively binds nitrogen molecules from atmospheric air, allowing for medical-grade oxygen of 85–95% concentration.
Two main types of molecular sieves are used: LiX (lithium-exchanged) and NaX (sodium-exchanged). They differ in nitrogen adsorption selectivity, oxygen separation efficiency, and regeneration requirements. The correct sieve type directly impacts the performance, durability, and stability of the concentrator.

In oxygen concentrators—both home and medical—the sieves come in:

  • replaceable cartridges (sieve bed replacements),
  • cartridges,
  • compact adsorption beds (sieve beds).

These elements require periodic replacement or regeneration during regular maintenance, ensuring optimal performance and high-quality oxygen delivery to patients.

Zeolite Molecular Sieves in Oxygen Concentrators: LiX and NaX

Oxygen concentrators are devices used to produce high-purity oxygen from atmospheric air. They are widely used both at home and in medical facilities—in oxygen therapy supporting the treatment of respiratory and cardiovascular diseases, as well as in conditions of hypoxia. Depending on their purpose, concentrators can be designed as portable individual devices or as stationary installations, supplying oxygen to multiple users simultaneously.

Their operation is based on Pressure Swing Adsorption (PSA/VPSA) technology, which involves the cyclic separation of air components using molecular sieves—specialized zeolite adsorbents. These sieves selectively capture nitrogen during compression, allowing the remaining stream to be enriched with oxygen. During decompression, the adsorbed nitrogen is desorbed back into the environment, and the cycle repeats. This process does not chemically wear the adsorbent, allowing for its repeated use.

In oxygen concentrators, two types of molecular sieves are most commonly used:

  • LiX (lithium zeolite type X) – characterized by higher selectivity for nitrogen and shorter cycle times. This enables greater oxygen efficiency at lower energy consumption, making them the preferred choice in modern, compact medical concentrators.
  • NaX (sodium zeolite type X) – known for good stability and lower cost, they are often used in older devices or less demanding applications where economic operation is a priority.

The choice of sieve type depends on the concentrator’s design and user requirements—from portable devices with low power consumption to high-efficiency stationary installations.

Molecular sieves used in oxygen concentrators differ in key adsorption properties, impacting the efficiency of the entire PSA/VPSA process. Below is a summary of the basic technical parameters of LiX and NaX sieves, including their selectivity for nitrogen, adsorption capacity, cycle time, and typical application areas. This aids in matching the sieve type to specific concentrator designs and user expectations.

Parameter NaX Molecular Sieves LiX Molecular Sieves
Physical Parameters
Form Spherical Spherical
Fraction Size 0.4-0.8 mm 0.4-0.8 mm
Bulk Density 660 kg/m³ 620 kg/m³
Process (Operational) Parameters
Oxygen Production Rate 1-5 L/min 1-20 L/min
Pressure 1.4-2 bar 1-2 bar
Adsorption Parameters
N₂/O₂ Selectivity Ratio ≥3 ≥6.2
N₂ Adsorption Capacity (25°C) >8 ml/g >22 ml/g
Oxygen Recovery Rate 30-45% 45-68%
Oxygen Purity 93% ± 3% 93% ± 3%
Comparison of LiX and NaX
Comparison of LiX and NaX

Using the right type of molecular sieve is crucial for achieving the required oxygen purity—typically ≥93% ±3% by volume. In practice, oxygen concentrators use two main types of molecular sieves: NaX (sodium zeolite type X) and LiX (lithium zeolite type X). Both are based on the same crystal structure but differ in their adsorption properties and operational efficiency.

NaX – The Economical Solution

NaX molecular sieves feature a lower purchase cost and greater tolerance for deviations from operating conditions. They are primarily used in basic, lower-capacity oxygen concentrator models. Due to moderate nitrogen selectivity and lower adsorption capacity, their use may require larger bed volumes or acceptance of lower process efficiency. NaX is a suitable solution where simplicity, material availability, and a limited investment budget are priorities.

LiX – The High-Performance Adsorbent

LiX sieves offer significantly higher nitrogen/oxygen separation selectivity and greater adsorption capacity, allowing for smaller bed volumes while maintaining the concentrator’s full performance. This enables the design of more compact, energy-efficient devices with longer lifespans and greater resistance to mechanical wear. Due to their higher unit cost and stricter system precision requirements, LiX sieves are mainly used in medical-grade concentrators and modern, high-efficiency portable systems.

Selection Recommendations

  1. First, always follow the concentrator manufacturer’s recommendations. Devices designed for a specific sieve type should not be operated with a material having different adsorption properties.
  2. For budget-friendly devices and applications with lower technical requirements, selecting NaX sieves is recommended.
  3. For concentrators that require a compact design, low energy consumption, and high durability, using LiX sieves is preferred.

Contact us to choose the right type of molecular sieve for your concentrator and optimize operating costs.

Our molecular sieves (LiX and NaX) for oxygen concentrators can be used as replacement cartridges in many commercial medical devices—both stationary and portable.

Stationary 0–5 lpm e.g., Caire AirSep VisionAire 5, Caire Companion 5, AirSep NewLife Elite, Inogen At Home GS100, Philips Respironics EverFlo Q, Invacare Perfecto2 V, DeVilbiss 525DS, GCE Nuvo Lite Mark 5.
Stationary 0–10 lpm e.g., Caire AirSep NewLife Intensity, Philips Millennium M10, Invacare Platinum 10L, DeVilbiss 1025DS, GCE Nuvo 8.
Portable – Pulse Flow e.g., Inogen One G3–G5, Caire FreeStyle 3/5, Philips SimplyGo Mini, Invacare Platinum Mobile, Invacare XPO2, ResMed Mobi, O2 Concepts Oxlife Freedom, GCE Zen-O Lite (RS-00600), Precision Medical EasyPulse PM4130/PM4150.
Portable – Continuous Flow e.g., Caire Eclipse 5, Philips SimplyGo, Drive DeVilbiss iGo, O2 Concepts Oxlife Independence, GCE Zen-O (RS-00500), Precision Medical EasyPulse PM4400.

The models listed above are examples—we prepare cartridges and sieves for specific devices and required flow rates (pulse/continuous).
Why Our Sieves?

  • Compatibility: Matched grain size and charge mass for the concentrator.
  • Performance: High N₂ selectivity and stable operation during variable PSA cycles.
  • Durability: Low dust content, controlled initial moisture, and sealed packaging.

Names and trademarks belong to their respective owners. The offered cartridges/sieves are compatible replacement parts; they are not OEM products.

Precision, Reliability, Performance

Looking for the right molecular sieves for an oxygen concentrator but unsure which will be best? Contact us – we’ll help you choose LiX or NaX sieves tailored to your device and expectations.

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Zeolite Molecular Sieves in Oxygen Concentrators: LiX and NaX – Barrels