Activated alumina desiccant for compressed air and gas drying

We are a European B2B supplier of activated alumina desiccant for compressed air dryers and process gas drying. We supply beads, also called activated alumina balls, and granular activated alumina for bulk orders and smaller quantities. Activated alumina is also known as activated aluminium oxide (Al₂O₃). Selected grades are used in TSA/PSA systems and air separation unit (ASU) pre-purification.

We supply original products and equivalents of Axens AxSorb A and AxSorb D, Jalon JLAA and BASF F-200. Most adsorbents are dispatched within 2-5 working days.

Request a quote

Activated alumina adsorbent in bead and grain form for industrial gas and liquid drying.

Description

Activated alumina granules and beads in glass dishes
Activated alumina granules and beads in glass dishes

Industrial activated alumina for gas drying and adsorption systems

Activated alumina adsorbent is a porous material that removes water vapour from compressed air and process gases, which makes it a common gas drying adsorbent. Drying grades can be regenerated by heating or by pressure swing, depending on the system.

We help you select the grade and particle size for your process. Selection depends on adsorption capacity, mechanical strength, regeneration method, operating conditions and acceptable pressure drop. See the Grades and originals tab for the available sizes and brands.

Activated alumina for compressed air dryers

Activated alumina is the standard air dryer desiccant in heatless (cold-regenerated) adsorption dryers. These dryers regenerate the bed with part of the dried air, expanded to atmospheric pressure, without heating. Activated alumina is also used in heat-regenerated dryers, where a typical regeneration temperature is about 170-200 °C, according to adsorbent manufacturer data. In thermal swing adsorption (TSA) units for process gas drying, activated alumina is typically regenerated at 200-300 °C; the higher temperature is used when a drier product gas is required. The required conditions depend on the grade and the system design.

Activated alumina is used for pressure dew point targets of -25 to -40 °C in heatless and standard externally heat-regenerated dryers. The achievable value depends on the dryer design and operating conditions. Under ISO 8573-1, water class 3 requires a pressure dew point of -20 °C or lower, class 2 requires -40 °C or lower, and class 1 requires -70 °C or lower. For -70 °C, dryer and adsorbent manufacturers use 4A molecular sieve.

For a replacement bed, send the dryer manufacturer and model, the fill mass or vessel dimensions, the bead size, the dew point target and the regeneration method. Our article Desiccants for compressed air dryers compares silica gel, activated alumina and molecular sieve.

Activated alumina for gas drying

Activated alumina removes water vapour from air, nitrogen, oxygen, hydrogen and other technical gases before further processing, storage or use. To select a grade, we need the gas composition, inlet moisture, flow rate, operating pressure, contaminants and regeneration conditions.

Regeneration in PSA and TSA systems

In temperature swing adsorption (TSA), the drying bed is regenerated by heating and a gas flow that removes the released moisture. In pressure swing adsorption (PSA), pressure reduction and purge gas allow the moisture to desorb. The cycle must match the grade and the equipment design.

For bead sizes, granules and brands, see the Grades and originals tab. Claus catalysts and grades impregnated with potassium permanganate are also available; see the Application tab for details.

How activated alumina holds water

Chart: the heat of water adsorption on three activated alumina grades falls as the bed loads up and approaches the heat of condensation of water, while 13X molecular sieve stays at about 73 to 75 kJ/mol.Chart: the heat of water adsorption on three activated alumina grades falls as the bed loads up, while 13X molecular sieve stays high.

Activated alumina binds water in two ways. On a dry bed, the first water molecules react with the alumina surface and form hydroxyl groups; this water is held strongly, with a heat of adsorption well above the heat of condensation of water. As the loading grows, further water is held by hydrogen bonds and condenses in the pores, and the heat of adsorption falls towards that of liquid water. Over most of its capacity, activated alumina therefore needs less energy for regeneration than 13X molecular sieve, which binds water strongly up to full loading.

Product features

Activated alumina beads and granules in three glass jars
Activated alumina beads and granules in three glass jars

Properties of activated alumina drying grades

The properties below describe our activated alumina drying grades. Catalysts and grades impregnated with potassium permanganate have separate specifications.

Abrasion and crush resistance

Activated alumina is an adsorbent with high mechanical resistance to abrasion and crushing. This supports stable operation in demanding applications such as compressed air dryers, process gas drying units, adsorption columns and selected water purification systems.

Good abrasion resistance also helps reduce dust formation during loading and operation. Properly selected activated alumina can therefore help reduce the risk of dust-related clogging of downstream fittings, valves and adsorber outlet elements.

Thermal stability

Activated alumina is a mineral-based adsorbent with good thermal stability. This allows it to be used in drying and regeneration processes where elevated temperatures occur, including thermally regenerated adsorption systems.

The final operating temperature range should always be verified against the technical data sheet of the selected product grade.

Resistance to liquid water

Our Class A and Class D drying beads are resistant to liquid water; Class D has the higher mechanical strength. They can be used where water vapour in the gas may condense, for example during start-up, upset conditions or variable process operation. Check the technical data sheet of the selected grade for its operating limits.

High water vapour adsorption capacity

Activated alumina Al₂O₃ has a porous structure and high specific surface area, which provide good water vapour adsorption capacity in industrial drying systems. The technical data sheet for our Class D drying beads (2-5 mm) lists a static water adsorption capacity of 21.5% by weight at 60% relative humidity.

This value does not determine the required bed mass or the dryer cycle time. Working capacity depends on temperature, pressure, inlet moisture, flow rate, bed design and regeneration conditions.

Multiple regeneration cycles

Drying grades can be used over repeated adsorption and regeneration cycles, with pressure swing or thermal regeneration depending on the installation. The regeneration method and operating conditions must match the selected grade and the dryer design.

Storage before loading

Keep the product in its sealed packaging in a dry place until loading. Close opened containers carefully to prevent moisture uptake and contamination. Follow the loading and start-up instructions for the selected grade and equipment.

Application

Activated alumina adsorption applications in gas drying, liquid purification, and water purification
Activated alumina adsorption applications in gas drying, liquid purification, and water purification

Industrial applications of activated alumina

The applications below use different grades of activated alumina. The grade is selected for the medium, the operating conditions and the required outlet quality.

Compressed air drying

Activated alumina is widely used in heatless and heat-regenerated adsorption dryers for compressed air. Dryer types, pressure dew points and regeneration temperatures are described in the Description tab.

Process gas drying

Selected grades remove moisture from process gases. The gases and the information needed to select a grade are listed in the Description tab.

Drying selected liquids

Selected grades, including BASF F-200 and Jalon JLAA, are used to remove water from liquids. Grade selection depends on the liquid composition and the operating conditions.

Natural gas, LNG and LPG applications

Activated alumina may be used in drying systems for hydrocarbon gas streams, including natural gas and selected LNG or LPG-related applications. The final material selection depends on gas composition, pressure, temperature, water content, required outlet specification and compatibility with the overall process design.

TSA/PSA systems and adsorption units

Activated alumina can operate in adsorption systems regenerated by pressure swing or temperature swing methods. It is used in fixed-bed adsorbers, drying columns and multi-layer adsorbent beds where repeated adsorption and desorption cycles are required.

Air separation pre-purification units

In air separation units (ASU), activated alumina is commonly used as a drying layer or protective pre-bed before molecular sieve in the pre-purification section. It reduces the water load on downstream adsorbents and supports stable operation of the purification section before the cold box.

Protection of industrial tank vent and breather systems

Activated alumina can be used in selected vent and breather systems for industrial tanks, where moisture control is required to limit humidity ingress into stored materials. Suitability depends on the tank system, air exchange rate, operating environment and required level of moisture protection.

Purification of transformer oils and lubricants

Selected grades of activated alumina remove residual organic acids from transformer oils and lubricants. Suitability should be verified based on liquid composition, process conditions and required documentation.

Activated alumina catalysts for the Claus process

Selected activated alumina catalyst grades are used in sulphur recovery units. They promote the Claus reaction between hydrogen sulphide (H₂S) and sulphur dioxide (SO₂), which produces elemental sulphur and water. BASF DD-431 is also designed for the conversion of COS and CS₂ in the first converter.

Claus catalyst grades, including BASF DD-431, S-100 and S-400, are supplied on request. Selected grades are also used as catalysts in other chemical processes. Selection depends on the process and the catalyst specification.

Activated alumina impregnated with potassium permanganate

Grades impregnated with potassium permanganate (KMnO₄) are used for chemical filtration of air and inert gases. Grades such as Alphachem 8 remove hydrogen sulphide (H₂S), mercaptans, sulphur dioxide (SO₂), nitrogen oxides (NOx), formaldehyde and ethylene. The pollutants are removed by adsorption, absorption and chemical reaction.

Typical uses are odour control at wastewater treatment plants, protection of electronics manufacturing and data centres against corrosive gases, and ethylene removal during the storage and transport of fruit and vegetables. We supply 8% KMnO₄ beads of about 3 mm and 12% KMnO₄ beads of 1-2 mm or 2-4 mm. The grade is selected for the gases to be removed and their concentrations.

Fluoride removal from water streams

Activated alumina media in fixed-bed adsorption columns removes fluoride from water. Suitable grades include, for example, Axens ActiGuard AA. Some of these grades also remove arsenic. Performance depends on water chemistry, pH, contact time, flow rate, competing ions, bed design and the selected grade.

Grades and originals

Activated alumina granules, beads impregnated with potassium permanganate and white activated alumina beads
Activated alumina granules, beads impregnated with potassium permanganate and white activated alumina beads

Activated alumina grades, originals and equivalents

Grades we supply

  • Activated alumina (Al₂O₃): CAS 1344-28-1, EINECS 215-691-6.
  • Available forms and sizes, depending on the grade and application: beads of 1.5-3, 2-5, 3-4, 3-5 and 4-8 mm, and granules of 0.6-1.5 and 1-3 mm.
  • Activated alumina for fluoride and arsenic removal from water, for example Axens ActiGuard AA.
  • Activated alumina impregnated with potassium permanganate: 8% KMnO₄ beads of about 3 mm and 12% KMnO₄ beads of 1-2 mm or 2-4 mm.
  • Activated alumina Claus catalysts, on request.

Originals and equivalents

Our range covers activated alumina grades known as Axens AxSorb A, AxSorb D and ActiGuard AA, Jalon JLAA and JLAZ, Compalox and BASF F-200. We supply original products and equivalent grades. Send us the name of the product you use, and we will provide the technical data sheet of a proposed equivalent for comparison.

Product names such as AxSorb, ActiGuard®, JLAA, JLAZ, Compalox, F-200, DD-431 and Alphachem belong to their respective owners and are used for reference only.

TDS and SDS for each grade are available on request.

Packaging, ordering and delivery

Packaging options include 5-litre plastic canisters and 60-litre and 200-litre drums, depending on the grade. The net mass of a drum depends on the grade and the manufacturer. Big bags are available on request. Most orders are dispatched within 2-5 working days.

Replacing the bed in your dryer or filling a new adsorber? Send us the product name or application, the quantity and the delivery location, and we will reply with a quotation and the technical data sheet. For a replacement bed, add the dryer or adsorber model and what it is filled with now, and we will propose a matching grade.

Request a quote

Activated alumina in 200-litre drums on a pallet

Frequently asked questions about activated alumina

  • Activated alumina is the standard fill for heatless dryers. Sorbead Air alumino-silicate gels are used in heat-regenerated dryers and have a lower typical regeneration temperature than activated alumina. In heatless dryers, 4A molecular sieve is used for a pressure dew point of -70 °C or when the inlet air is warmer than about 38 °C. The dryer manufacturer specifies the desiccant, particle size and fill mass.

    Molecular sieve takes up most of its capacity already at low humidity, which is why it reaches the lowest dew points. Activated alumina and silica gel adsorb water more gradually as humidity rises, and at high humidity they can hold more water than the sieve, depending on the grade.

    Chart: water vapour isotherms at 30 °C. 13X molecular sieve takes up about 20 g per 100 g below 5% relative humidity; three activated alumina grades and silica gel adsorb gradually and reach 18 to 42 g per 100 g at high humidity.Chart: water vapour isotherms at 30 °C for 13X molecular sieve, three activated alumina grades and silica gel.

  • Typical targets are -25 to -40 °C in heatless and standard externally heat-regenerated dryers. The result depends on the dryer design and operating conditions. For -70 °C, dryer and adsorbent manufacturers use 4A molecular sieve.

  • In a heatless dryer, part of the dried air is expanded to atmospheric pressure and used to regenerate the bed without heating. The vessels switch every few minutes. In heat-regenerated dryers, a typical regeneration temperature for activated alumina is about 170-200 °C, according to adsorbent manufacturer data. In thermal swing adsorption (TSA) units for process gas drying, it is typically 200-300 °C; the higher temperature is used when a drier product gas is required. Check the grade documentation and the dryer instructions for the required conditions, or ask us if the data sheet does not include them.

  • Sometimes, but the replacement must match the dryer design. In heat-regenerated dryers, 4A molecular sieve needs a regeneration temperature above 200 °C, so a dryer operating at 170-200 °C may not regenerate it enough for the required dew point. This does not apply to heatless regeneration. Before changing the material, check the regeneration method, bed cooling, cycle time and particle size in the dryer documentation.

  • Yes, we supply the original products. We also offer equivalent grades: send the name of the product you use now, and we will propose an equivalent with its technical data sheet for comparison.

  • Send the product name or application, the required quantity and the delivery location. For a replacement bed, include the dryer or adsorber model and any available data: current product, fill mass or vessel dimensions, particle size, medium, flow rate, operating pressure, inlet temperature, target dew point and regeneration method. For impregnated grades, also list the gases to be removed and their concentrations. The price depends on the grade, quantity and packaging and is given in the quotation.

Request a quote for activated alumina

Tell us which product or application you need and the required quantity. Include any available technical details so we can prepare a quotation.